{"id":299,"date":"2019-10-03T16:57:23","date_gmt":"2019-10-03T20:57:23","guid":{"rendered":"https:\/\/sites.bu.edu\/mcneely\/?page_id=299"},"modified":"2020-07-02T22:28:05","modified_gmt":"2020-07-03T02:28:05","slug":"research","status":"publish","type":"page","link":"https:\/\/sites.bu.edu\/mcneely\/research\/","title":{"rendered":"Research"},"content":{"rendered":"<h1>Active Projects<\/h1>\n<h2 id=\"ParaTemp\">Professor David Coker and Professor John Porco<\/h2>\n<ul>\n<li>\n<h4>ParaTemp<\/h4>\n<p><a href=\"\/mcneely\/files\/2019\/10\/ParaTemp.png\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/ParaTemp-636x374.png\" alt=\"\" width=\"636\" height=\"374\" class=\"alignleft size-medium wp-image-369\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/ParaTemp-636x374.png 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/ParaTemp-768x451.png 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/ParaTemp-1024x602.png 1024w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/ParaTemp.png 1210w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><br \/>\nBuilding upon the work of Dr. Thomas Heavey and in collaboration with the Coker research group and Porco research group, I am developing an &#8220;organic chemist&#8217;s&#8221; interface to sophisticated theoretical techniques used to sample the conformational space of complex molecules; in particular replica exchange molecular dynamics, otherwise known as parallel tempering.\n<\/li>\n<\/ul>\n<h2 id=\"Doerrer\">Professor Linda Doerrer<\/h2>\n<ul>\n<!-- \n\n<li>\n\n<h4>Excitation Spectra of pinF Ligated Lanthanides<\/h4>\n\n\n<a href=\"\/mcneely\/files\/2019\/10\/lnoc4.png\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/lnoc4-636x268.png\" alt=\"\" width=\"636\" height=\"268\" class=\"alignleft size-medium wp-image-380\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/lnoc4-636x268.png 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/lnoc4-768x324.png 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/lnoc4.png 895w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><br \/>\nBased on the synthetic work led by Professor Christopher Kotyk with spectroscopic analyses performed by Professor Ana de Bettencourt-Dias at University of Nevada-Reno and computational assistance from Dr. Ariel Hyre, I have developed a new protocol for the modeling of lanthanide spectroscopic properties. Spin-orbit coupling and scalar relativistic effects are significant for lanthanides, and they must be included in any treatment of spectroscopic properties. We have found that standard multi-reference perturbation theory (blue) is not successful for the full series of compounds that were synthesized and spectroscopically characterized. We have observed moderate success with a new protocol that models the ligands as being comprised of point charges only, and then uses MRCI methods to predict the excitation spectra of the systems (red). \n<\/li>\n\n\n\n\n<li>\n\n<h4>Sn Mossbauer Spectral Decomposition and Prediction<\/h4>\n\n\n<a href=\"\/mcneely\/files\/2019\/10\/snmoss-2.png\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/snmoss-2-636x305.png\" alt=\"\" width=\"636\" height=\"305\" class=\"alignleft size-medium wp-image-378\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/snmoss-2-636x305.png 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/snmoss-2-768x369.png 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/snmoss-2.png 821w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a>\nPhD Candidate Jessica Elinburg synthesized Sn(II) complexes ligated by the pin<sup>F<\/sup> ligand, and after Moessbauer characterization by the group of Professor Rainer P\u00f6ttgen, noticed some very peculiar behavior. By just varying the counter-cation used to crystallize the complex, the quadrupolar splitting of the tin center as determined by Moessbauer spectroscopy is increased by almost 0.5 mm\/s! I am working to help explain this behavior by calibrating a theoretical method vs. a standard tin Moessbauer series and also giving a 'chemical' explanation for the observed disparity in quadrupolar splitting.\n<\/li>\n\n --><\/p>\n<li>\n<h4>The Electronic Structure of Square-Planar Co(III) Systems<\/h4>\n<\/li>\n<p>\n<a href=\"\/mcneely\/files\/2019\/10\/Screenshot-6.png\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/Screenshot-6-636x213.png\" alt=\"\" width=\"636\" height=\"213\" class=\"alignleft size-medium wp-image-388\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Screenshot-6-636x213.png 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Screenshot-6.png 739w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><br \/>\nSpurred on by the interesting electronic structure that was observed for the square planar Co(III)(pin<sup>F<\/sup>)<sub>2<\/sub> system that was reported by the Doerrer group (<a href=\"https:\/\/doi.org\/10.1039\/C8CC04464C\">10.1039\/C8CC04464C<\/a>), I am currently doing a comprehensive investigation into the electronic structure of Co(III) square planar systems. In particular, I am investigating the detailed structural features that affect the relevant energy levels that result in the significant spin-orbit coupling observed in these systems. I am also looking at the electronic feature that causes the unexpected rhombicity observed in some of these systems.\n<\/ul>\n<p><!-- \n\n<h2 id=\"Porco\">Professor John Porco<\/h2>\n\n\n\n\n<ul>\n\n\n<li>\n\n<h4>Modeling of Transition States for [4+2] Concerted and Stepwise Processes<\/h4>\n\n\n<a href=\"\/mcneely\/files\/2019\/10\/chunchen.jpg\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/chunchen-636x107.jpg\" alt=\"\" width=\"636\" height=\"107\" class=\"alignleft size-medium wp-image-413\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/chunchen-636x107.jpg 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/chunchen-768x129.jpg 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/chunchen-1024x172.jpg 1024w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a>\nPhD candidate Chun Chen is studying the [4+2] cycloaddition of 2,6-dichlorobenzoquinone with ethyl 3-methylpenta-2,4-dienoate. I am assisting here with providing an explanation for the experimentally observed product distribution. Namely, that the terminal carbon on ethyl 3-methylpenta-2,4-dienoate exclusively binds to hydrated carbon on the other reactant. We have observed that this selectivity is driven by steric effects that are due to the asynchronicity of the mechanism. As can be seen above, the electronic structure of the 2,6-dichlorobenzoquinone reactant causes the [4+2] cycloaddition to attack the hydrated carbon faster than the chlorinated carbon due to pi-donation from the adjacent chlorine lone pair. We are quantifying these effects and Chun is helping complete her story with these computations.\n<\/li>\n\n\n<\/ul>\n\n --><\/p>\n<h2 id=\"Beeler\">Professor Aaron Beeler<\/h2>\n<ul>\n<li>\n<h4>Development of Scripts For QM Descriptor Production<\/h4>\n<p><a href=\"\/mcneely\/files\/2019\/10\/doug-1.png\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/doug-1-636x318.png\" alt=\"\" width=\"636\" height=\"318\" class=\"alignleft size-medium wp-image-411\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/doug-1-636x318.png 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/doug-1-768x384.png 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/doug-1-1024x512.png 1024w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/doug-1.png 1200w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><br \/>\nPhD candidate Doug Fraser is involved in an ambitious multi-component project. This project will develop a high-yield instrumental technique that rapidly identifies suitable reactants that will be combined with a database of structural predictors augmented by quantum-mechanical descriptors that will then be mined by the statistical department at BU to identify key descriptors that help predict reactivity. I am assisting Doug in developing scripting tools that will allow high-throughput calculations that automatically organizes and extracts descriptors so that the data can be mined by the statisticians.\n<\/li>\n<\/ul>\n<h2 id=\"Grinstaff\">Professor Mark Grinstaff<\/h2>\n<ul>\n<li>\n<h4>FMO Theory For Protecting Group Variation in Glycal+TCAI Production of beta-Lactams.<\/h4>\n<\/li>\n<p><a href=\"\/mcneely\/files\/2019\/10\/Screenshot-4.png\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/Screenshot-4-636x330.png\" alt=\"\" width=\"636\" height=\"330\" class=\"alignleft size-medium wp-image-383\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Screenshot-4-636x330.png 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Screenshot-4.png 750w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><br \/>\nPhD candidate Anant Balijepalli made the important observation that the [2+2] cycloaddition of glycals with TCAI is correlated with the electron-withdrawing power of glycal protecting groups. Anu synthesized a library of 18 electron-rich alkenes (glycals) with varied protecting groups to systematically elucidate the factors that influence their reactivity towards an electron-poor isocyanate (trichloroacetyl isocyanate). The experimentally determined reaction rates exponentially correlate with the computationally-determined HOMO-LUMO gap and NBO (natural bond orbital) valence energies. The electron withdrawing ability of the protecting groups, but not bulk, impact the electron density of the glycal allyloxocarbenium system when oriented pseudo-axially (i.e., stereoelectronics). In this conformation, ring \u03c3* (C-O) orbitals oriented anti-periplanar to the allyloxocarbenium system decrease glycal reactivity via negative hyperconjugation as protecting group electron withdrawal increases. Transition state calculations reveal that protecting group stereoelectronics direct the reaction to proceed via a concerted, asynchronous mechanism through a zwitterionic species, supported by a rate acceleration in polar reaction solvents (e.g., acetonitrile and nitromethane).\n<\/ul>\n<h2 id=\"straubgrinstaff\">Professor John Straub and Professor Mark Grinstaff<\/h2>\n<ul>\n<li>\n<h4>Mapping the PES of Poly-Amido-Saccharides.<\/h4>\n<\/li>\n<p><a href=\"\/mcneely\/files\/2019\/10\/hannah.jpg\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/hannah-636x316.jpg\" alt=\"\" width=\"636\" height=\"316\" class=\"alignleft size-medium wp-image-510\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/hannah-636x316.jpg 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/hannah-768x381.jpg 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/hannah-1024x508.jpg 1024w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/hannah.jpg 1144w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><br \/>\nHannah Caputo of the Grinstaff research group and PhD candidate Asange Bandara of the Straub research group collaborated on a project to elucidate the conformational space of sulfated polysaccharides and form a predictive model for the reactivity of the monomers and three-dimensional conformations of the polysaccharides. While Hannah has moved on, Asanga is continuing the research and has benchmarked and verified the force field in his work against QM calculations performed by Hannah and myself.\n<\/ul>\n<h2>Long-Term Projects<\/h2>\n<ul>\n<li>\n<h4>EPR Spectral Simulation<\/h4>\n<\/li>\n<p><a href=\"\/mcneely\/files\/2019\/10\/Screenshot-5.png\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/Screenshot-5-636x224.png\" alt=\"\" width=\"636\" height=\"224\" class=\"alignleft size-medium wp-image-385\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Screenshot-5-636x224.png 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Screenshot-5-768x270.png 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Screenshot-5-1024x360.png 1024w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Screenshot-5.png 1030w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><\/p>\n<p>Based on work done in my dissertation, I am continuing to develop a software package written in C++ that will do a full diagonalization of the Spin Hamiltonian matrix with a user-friendly interface. This program will be available to all groups in the department upon completion and includes helpful &#8216;guides&#8217; for students. The simulations can also be combined with ESS software to automate the dual experimental fitting\/theoretical prediction of EPR spectra. This program is an enhancement on currently available software packages in that it is 1) parallelized; 2) highly efficient; 3) able to run in a &#8220;black-box&#8221; fashion.<\/p>\n<li>\n<h4>ORCA NBO<\/h4>\n<\/li>\n<p><a href=\"\/mcneely\/files\/2019\/10\/onbo.jpg\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/onbo-636x217.jpg\" alt=\"\" width=\"636\" height=\"217\" class=\"alignleft size-medium wp-image-497\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/onbo-636x217.jpg 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/onbo-768x262.jpg 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/onbo-1024x349.jpg 1024w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><\/p>\n<p>Although the latest version of the ORCA ESS contain NBO options when linked to a exiting NBO executable, the ability of ORCA to interface with NBO is rather limited, and it requires a separate purchase of the GENNBO code. I am writing the NBO code from scratch with C++ and the Eigen library to give full control of all NBO options to users who prefer the ORCA ESS. In addition to giving greater access to the NBO functionalities and spurring further modifications and analysis tools based on NBO localization constructs, the new program will be able to interactively cooperate with ORCA to perform functions such as $DEL and $NEDA. I currently have a functional subroutine that will generate NBO formatted archive files from an ORCA output file that can be used as input for the standalone GENNBO executable. Please contact me if you&#8217;d like to use the program.<\/p>\n<li>\n<h4>Customizable Interfaces For Computational Engines<\/h4>\n<\/li>\n<p><a href=\"\/mcneely\/files\/2019\/10\/Customizable.jpg\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/Customizable-636x176.jpg\" alt=\"\" width=\"636\" height=\"176\" class=\"alignleft size-medium wp-image-504\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Customizable-636x176.jpg 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Customizable-768x213.jpg 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Customizable-1024x284.jpg 1024w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/Customizable.jpg 1184w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><br \/>\nAlthough they are sometimes treated as such, computational methods are not &#8220;black-box&#8221; methods. Particularly in light of the density functional stew that is available, researches must robustly identify the proper computational technique to approach different problems. The goal of this project is to create tailored &#8220;black-boxes&#8221;. Based on modern literature and my expertise, interfaces for different research will be designed so that the desired outcome is robustly achieved. Each research group generally studies systems that can be broadly grouped together, and thus each group will contain their own interface that reduces the bottleneck of incoming students mastering the command line and basic quantum chemistry before obtaining results.<\/p>\n<li>\n<h4>Direct Dynamics and Variational TST For ORCA<\/h4>\n<\/li>\n<p><a href=\"\/mcneely\/files\/2019\/10\/odyn.jpg\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/odyn-636x244.jpg\" alt=\"\" width=\"636\" height=\"244\" class=\"alignleft size-medium wp-image-499\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/odyn-636x244.jpg 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/odyn-768x294.jpg 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/odyn-1024x392.jpg 1024w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><br \/>\nI have completed a beta version of a C++ program that interfaces with the ORCA ESS to perform quasi-classical direct dynamics calculations. The program is largely based on Singleton&#8217;s PROGDYN, but is being extended to include Variational TST calculations based on the work of Truhlar et al. While ORCA recently developed their own MD capabilities that are built into the binaries, my work gives users full access to the dynamics options, and it also can be tailored for specific systems. Shown above is a representative results displaying a system that is predicted by classical TST to preferrably pass through a transition state that is not the experimentally determined reaction pathway. Please contact me if you&#8217;d like to obtain the program or would like a custom modification made.\n<\/ul>\n<h1>Other Research Interests<\/h1>\n<h2>Electronic Structure of Non-Innocent Ligands<\/h2>\n<p><a href=\"\/mcneely\/files\/2019\/05\/GilSpinDens.jpg\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/05\/GilSpinDens-636x232.jpg\" alt=\"\" width=\"636\" height=\"232\" class=\"alignleft size-medium wp-image-245\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/05\/GilSpinDens-636x232.jpg 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/05\/GilSpinDens-768x280.jpg 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/05\/GilSpinDens.jpg 837w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><\/p>\n<p>The pyridine-2,6-diimine (PDI) ligand has a wealth of documentation pertaining to its uncanny ability to stabilize a number of transition metal reactions.  This interest was largely prompted by the works of Gibson  and Brookhart  on cobalt and iron-based olefin polymerization using PDI-catalyzed systems.  Following these studies, other groups entered the foray and immense progress has been made.<\/p>\n<p>Several groups have further explored the ability of PDI systems to catalyze olefin polymerization\/oligomerization, dimerization, and hydrogenation. Chirik et al. and others have shown that PDI systems promote a number of other functionalizations including hydroboration reactions  and hydrosilations. There have also been a large number of studies demonstrating the ability of PDI systems to activate C-H bonds and catalyze C-C bond formation. Burger et al. demonstrated the ability of a PDI-anchored Iridium system to catalytically promote nitrogen fixation.   Still other groups have shown N-N bond cleavage promoted by PDI systems , C-O functionalization, O<sub>2<\/sub> activation,  and N-H activation. Gilbertson recently demonstrated the ability of the Fe2+(PDI)X2 (X = Cl-, Br-) system to catalytically reduce carbon dioxide to carbon monoxide, a highly desirable reaction.<\/p>\n<p>Much of the work mentioned above used Density Functional Theory (DFT) or a combination of DFT and Broken Symmetry (DFT-BS) to theoretically characterize the PDI systems. There have been other successful applications of DFT-BS techniques to PDI systems that were not mentioned above. There are a surprisingly small amount of multi-reference investigations into the electronic structure of the PDI ligand and transition metal complexes containing the PDI ligand. Guihery et al. used CASSCF(2,2) and difference dedicated configuration interaction (DDCI) techniques to study how the electronic structure of PDI was affected by different point charges located at the metallic position. Burger et al. used MRMP2(10,10) technique to characterize an Iridium-Nitride triple bond stabilized by the PDI scaffold. This complex is involved in catalytic N2 fixation.<\/p>\n<p>I have shown the following: First, while DFT-BS results are useful and often correlate well with experimental results, they can also be ambiguous. Different DFT-BS approaches will be energetically similar, but only one of the approaches agrees with experiment. This is a serious problem if one is studying a system that has not been characterized experimentally.  Second, the choice of active space when studying PDI-Fe(II) systems must be made very carefully. If the proper choice of active space is not made, the electronic structure obtained via MRMP2\/CASSCF methods does not correlate with experiment. Third, I have shown the correct electronic structure of Fe2+(PDI)X2 (X = Cl-, Br-) based on MRMP2(14,14) results.<\/p>\n<h2>Electronic Structure of Curved Polyaromatic Systems<\/h2>\n<p><a href=\"\/mcneely\/files\/2019\/10\/LiNMR.png\"><img loading=\"lazy\" src=\"\/mcneely\/files\/2019\/10\/LiNMR-636x250.png\" alt=\"\" width=\"636\" height=\"250\" class=\"alignleft size-medium wp-image-401\" srcset=\"https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/LiNMR-636x250.png 636w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/LiNMR-768x301.png 768w, https:\/\/sites.bu.edu\/mcneely\/files\/2019\/10\/LiNMR.png 991w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Active Projects Professor David Coker and Professor John Porco ParaTemp Building upon the work of Dr. Thomas Heavey and in collaboration with the Coker research group and Porco research group, I am developing an &#8220;organic chemist&#8217;s&#8221; interface to sophisticated theoretical techniques used to sample the conformational space of complex molecules; in particular replica exchange molecular [&hellip;]<\/p>\n","protected":false},"author":10766,"featured_media":0,"parent":0,"menu_order":5,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"_links":{"self":[{"href":"https:\/\/sites.bu.edu\/mcneely\/wp-json\/wp\/v2\/pages\/299"}],"collection":[{"href":"https:\/\/sites.bu.edu\/mcneely\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/sites.bu.edu\/mcneely\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/sites.bu.edu\/mcneely\/wp-json\/wp\/v2\/users\/10766"}],"replies":[{"embeddable":true,"href":"https:\/\/sites.bu.edu\/mcneely\/wp-json\/wp\/v2\/comments?post=299"}],"version-history":[{"count":50,"href":"https:\/\/sites.bu.edu\/mcneely\/wp-json\/wp\/v2\/pages\/299\/revisions"}],"predecessor-version":[{"id":915,"href":"https:\/\/sites.bu.edu\/mcneely\/wp-json\/wp\/v2\/pages\/299\/revisions\/915"}],"wp:attachment":[{"href":"https:\/\/sites.bu.edu\/mcneely\/wp-json\/wp\/v2\/media?parent=299"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}